Atomic force microscopy (AFM) is coupled with time-domain two-dimensional infrared (2DIR) spectroscopy to develop AFM-2DIR nanospectroscopy, which combines the spatial precision of AFM with the rich spectroscopic information provided by 2DIR spectroscopy. Application of this method reveals the anharmonicity of a carbonyl vibrational mode and the possible energy transfer pathways of hyperbolic phonon polaritons in isotope-rich hexagonal boron nitride.
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References
Chen, X. et al. Modern scattering‐type scanning near‐field optical microscopy for advanced material research. Adv. Mater. 31, 1804774 (2019). A review article that presents scattering-type scanning near-field optical microscopy with optical detection.
Mathurin, J. et al. Photothermal AFM-IR spectroscopy and imaging: status, challenges, and trends. J. Appl. Phys. 131, 010901 (2022). A review article that presents AFM-IR with mechanical detection.
Hamm, P. & Zanni, M. Concepts and Methods of 2D Infrared Spectroscopy (Cambridge Univ. Press, 2011). This book reports the underlying concepts and technical details of 2DIR.
Wang, L., Wang, H. & Xu, X. G. Principle and applications of peak force infrared microscopy. Chem. Soc. Rev. 51, 5268–5286 (2022). A review article that discusses the development of PFIR.
Dai, S. et al. Tunable phonon polaritons in atomically thin van der Waals crystals of boron nitride. Science 343, 1125–1129 (2014). This paper reports the detection of phonon polaritons in a layered van der Waals crystal (h-BN) and presents simulations on the dispersion relations of phonon polaritons.
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This is a summary of: Xie, Q. et al. Atomic-force-microscopy-based time-domain two-dimensional infrared nanospectroscopy. Nat. Nanotechnol. https://doi.org/10.1038/s41565-024-01670-w (2024).
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Combining two-dimensional infrared spectroscopy with atomic force microscopy. Nat. Nanotechnol. (2024). https://doi.org/10.1038/s41565-024-01671-9
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DOI: https://doi.org/10.1038/s41565-024-01671-9