Inorganics, Volume 12, Issue 6 (June 2024) – 34 articles
Cover Story (view full-size image):
A synthetic study was conducted to explore the reactivity towards tetrabutylammonium cyanide of a series of dinuclear bis-cyclopentadienyl carbonyl complexes of iron and ruthenium, containing a varying unsaturated hydrocarbyl ligand, occupying a bridging coordination site. Depending on the distinct cases, cyanide addition occurs at either the metal centers or the hydrocarbyl moiety, and subsequent intramolecular cyanide migration can be thermally induced, directed by the cooperativity of the dimetallic framework. It was revealed that IR and NMR spectroscopy are potent tools to elucidate the outcomes of the reactions, with DFT calculations assisting in understanding the structural and thermodynamic aspects. View this paper
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