Molbank, Volume 2024, Issue 2 (June 2024) – 43 articles
Cover Story (view full-size image):
The compound 3,5-di-(pyridin-4-yl)-1,2,4-thiadiazole (L1) is known to react with metal ions to form coordination polymers and polygons. In this work, we decided to explore the reactivity of L1 with 1,4-diiodotetrafluorobenzene (1,4-DITFB) to evaluate the possibility of preparing supramolecular structures using σ-hole interactions between halogen-rich compounds and pyridine tectons. Notably, 1,4-DITFB owns two iodine atoms disposed in the phenyl ring, which are activated by the presence of four fluorine substituents. We report here on the synthesis and characterization of the novel halogen-bonded co-crystal of 3,5-di-(pyridin-4-yl)-1,2,4-thiadiazole and 1,4-diiodotetrafluorobenzene. View this paper
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