Molecules, Volume 29, Issue 13 (July-1 2024) – 295 articles
Cover Story (view full-size image):
The dynamic unusual transformation of Ru-pyrrole carboxylate species is afforded by a long acetonitrile boiling process, satisfying the yield of the heteroleptic k2(N,O)- bonding mode from the original k2(O,O)- coordination. The π-delocalized air- and moisturizing stable solvento-neutral species reveal antimicrobial properties. The proposed DFT-calculated mechanisms disclose low-energy paths, where H2 release plays a crucial role. According to spectroscopic and X-ray structural data, the isolated fused 5-membered Ru-pyrrole aldehyde derivatives shed further light on the constitutional selective formation of ethenoyl azafulvene or cyclized pyrrole aldehyde species. In line with the Pearson’s anti-symbiotic selection, the hetero-anionic N- or O- hard functions both exhibit major stabilization in trans-locating the relative CO-ligands. View this paper
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