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. 2021 Jan 1:750:141208.
doi: 10.1016/j.scitotenv.2020.141208. Epub 2020 Aug 2.

Reconstruction of mining activities in the Western Alps during the past 2500 years from natural archives

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Reconstruction of mining activities in the Western Alps during the past 2500 years from natural archives

F Carvalho et al. Sci Total Environ. .

Abstract

The geochemical analysis of natural archives can improve our knowledge of past mining activities and their environmental imprint. The sedimentary records from the Hasli-Aare floodplain (Bernese Alps) over the last 2500 years were analysed for metals. Evidence of past mining contamination was obtained from the XRF analyses of iron, copper, zinc and lead. These results were analytically and statistically processed to produce a metal content index. Positive metal anomalies indicate four major pulses of contamination coinciding with the end of the Iron Age, from the end of the Roman Period to the Early Medieval Period, the Late Medieval Period, and the Modern Period. These pulses show good agreement with local historical sources of mining in the Hasli-Aare catchment, dating back to the beginning of the 15th century. Furthermore, they are in phase with anthropogenic pollution trends inferred from glacier ice cores, lake sediments and peat bogs across the Western Alps, most notably during the Roman, Late Medieval and Modern Periods. However, close comparison between these records can show some differences, suggesting local variations in mining activities and/or a lag in metal transfer. The reconstructed periods of anthropogenic metal pollution are located in their political, economic and social contexts and compared with the climate periods of central Europe.

Keywords: Floodplain sediments; Geochemistry; Historical mining; Late Holocene; Metal content; Western Alps.

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Conflict of interest statement

Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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