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Petroleomics: Advanced Characterization of Petroleum-Derived Materials by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS)

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Asphaltenes, Heavy Oils, and Petroleomics

Abstract

The high mass resolving power and mass accuracy of FT-ICR MS allow for the resolution and elemental composition assignment of thousands of species in petroleum-derived materials. Here, we report its application to heavy crude oils, associated production deposits, and isolated asphaltenes to reflect recent advances in the characterization of complex mixtures, as well as low-resolution mass spectrometry experiments aimed at verifying suspected multimer formation. Electrospray ionization (ESI), field desorption/ionization (FD/FI), electron ionization (EI), and atmospheric pressure photoionization (APPI) FT-ICR MS results are discussed. ESI results reveal the compositional complexity of the most polar species in crude oil.

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Authors
  1. Ryan P. Rodgers
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  2. Alan G. Marshall
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Editors and Affiliations

  1. Schlumberger-Doll Research, 36 Old Quarry Road Ridgefield, Connecticut, 06877, United States

    Oliver C. Mullins

  2. Vanton Research Laboratory, Inc., 7 Olde Creek Place, Lafayette, California, 94549, United States

    Eric Y. Sheu

  3. Schlumberger Oilfield Services, Edmonton, Alberta, T6N 1M9, Canada

    Ahmed Hammami

  4. Chemistry and Biochemistry, National High Magnetic Field Laboratory at Florida State University, 1800 East Paul Dirac Drive, Tallahassee, FL, 32310-4005, United States

    Alan G. Marshall

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Rodgers, R.P., Marshall, A.G. (2007). Petroleomics: Advanced Characterization of Petroleum-Derived Materials by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS). In: Mullins, O.C., Sheu, E.Y., Hammami, A., Marshall, A.G. (eds) Asphaltenes, Heavy Oils, and Petroleomics. Springer, New York, NY. https://doi.org/10.1007/0-387-68903-6_3

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